Molarity vs Normality vs Molality: Concentration Units Explained
Molarity, normality, and molality all describe how concentrated a solution is, but they measure different things and are used in different situations. This guide clears up the confusion with definitions, formulas, and worked examples.
2026年7月3日
Molarity (M): moles per liter of solution
Molarity is moles of solute per liter of solution: M = n / V. It is the default unit in general chemistry and stoichiometry because volumes are easy to measure with a flask or cylinder.
Its one weakness is temperature: liquid volume expands and contracts with heat, so a solution's molarity shifts slightly as temperature changes. For most bench work at room temperature this is negligible.
Normality (N): equivalents per liter
Normality measures equivalents of reactive species per liter: N = M × n, where n is the equivalence factor (replaceable H+, OH-, or electrons). It is most useful in acid-base titrations and redox chemistry.
For example, 0.5 M sulfuric acid (H2SO4) is 1 N because each mole provides two acid equivalents. Normality lets you compare reacting capacity directly rather than raw moles.
Molality (m): moles per kilogram of solvent
Molality is moles of solute per kilogram of solvent: m = n / kg. Because it is based on mass, not volume, it does not change with temperature — which is why it is the correct unit for colligative properties like boiling-point elevation and freezing-point depression.
When to use which: molarity for everyday stoichiometry, normality for titrations, and molality for temperature-sensitive or colligative-property calculations. Dedicated calculators convert between them in seconds.
Tools mentioned in this guide
- Molarity CalculatorMolarity calculator free — find M, moles, or volume with M=n/V. Convert mass to molarity using formula lookup. Instant chemistry in your browser.
- Normality CalculatorNormality calculator free — convert N, molarity, and equivalents per mole. Find normality from mass and volume. Chemistry titration prep in your browser.
- Molality CalculatorMolality calculator free — find mol/kg from moles and solvent mass. Convert grams to molality using formula lookup. Chemistry in your browser.
- Solution Concentration CalculatorSolution concentration calculator free — molarity, mass/volume, and dilution (C1V1=C2V2). Chemistry lab prep in your browser, no signup.
よくある質問
- What is the difference between molarity and molality?
- Molarity is moles per liter of solution and depends slightly on temperature; molality is moles per kilogram of solvent and does not. Use molarity for general stoichiometry and molality for colligative properties.
- When should I use normality instead of molarity?
- Use normality for acid-base titrations and redox reactions, where what matters is the number of reactive equivalents (H+, OH-, or electrons) rather than raw moles.